Jerry lin, chair mary lind david nielsen arizona state university august 2014. Pervaporation membrane chemical process engineering. Enhanced pervaporation performance of multilayer pdmspvdf. Novel perfluorinated polymerbased pervaporation membranes. As can be seen, the pdmsvtos membrane prepared in this research showed higher separation and lower permeation flux than those pdms membranes crosslinked with taos reported for pervaporation removal of ethanol from dilute aqueous solution. Studies have shown that pervaporation membrane system can offer energy savings of 35% over conventional distillation. Pervaporation pv is applied in liquid mixture separation by using nonporous membranes.
Pebax membranes for water desalination by pervaporation. Polymerceramic composite membranes and their application in. Selectivity reflects the intrinsic properties of the membrane. Taking into account the close similarity between pervaporation and vapour permeation techniques, a method for employing pervaporation flux data in the modelling of vapour permeation modules is.
The esterification reaction is reversible and has low yield. Vtos crosslinked pdms membranes for recovery of ethanol from. The feed liquid is directly in contact with one side of the membrane, and the permeation of target compounds through the membrane, in a vapour phase, is achieved by the difference in chemical potential gradient established by a difference in the partial pressure. The components of the liquid that move through the membrane are vaporized by the low pressure, removed and condensed. Pervaporationmt5009 analyzing hitech opportunities semester 2, 20112012 see siew hui a0077625x too kim hui a0077025j hubert giam a0082070r chua wei sun a0082022x damien poh weiye a0076856m linda wibisono a0077098n 2. Review fundamentals and applications of pervaporation. Ion exchange membrane processes electrodialysis 417 10. The separation mechanism of the pervaporation process predominantly relies on the preferential sorption and diffusion of the target component through the membrane. Pervaporation membrane mass spectrometry for investigating membrane mass transport phenomena pervaporation. Synthesis and modification of polymer membranes for. The pv performance of a membrane is usually expressed in terms of the permeation. Pervaporation, in its simplest form, is an energy efficient combination of membrane permeation and evaporation.
Pervaporation of ethanolwater mixture using pva zeoliteclay 169 normally, the pervaporation process is separated into three steps. Membrane 120 the separation of alcoholwater mixtures by pervaporation has been preferentially carried out through hydrophobic membranes because it is more practical to permeate alcohol through the membrane. In the pv process, the membrane plays the most pivotal role and is of. A for example, with the low temperatures and pressures involved in pervaporation, it often has cost and performance advantages for the separation of constantboiling azeotropes. Pervaporation is a membrane separation process used to separate mixture of dissolved solvents.
Introduction pervaporation and vapour permeation are similar membrane based separation processes whose basic difference lies in the physical state of the feed stream, which is a liquid in the former case and a vapour in the latter. Petro seps membrane distillation aqua sep systems can. Fundamental and applied aspects of liquid separation by means of pervaporation through polymeric membranes are considered. Surface free energies and interfacial free energies were calculated from contact angles to characterize hydrophilicity of the polyimide membranes. Pervaporation of ethanolwater mixture using polymeric membrane.
In the desalination of 38 gl seawater by pv, rejection was well above the minimum required for high quality potable water. Membrane transport properties of pervaporation and vapor. It allows the desired components of the liquid feed to read more. Principal of operation the membrane acts as a selective barrier between the two phases. Pervaporation of flavors with hydrophobic membrane springerlink. Separation of liquids by pervaporation through polymeric. A dense intergrown zeolite crystal layer of about 30. Compared with pervaporation, vapor permeation effectively increases the permselectivity of water. A water bath was used to heat the feed solution to the desired temperature the heater had a thermostat and a thermometer. Enhanced pervaporation performance of multilayer pdmspvdf composite membrane for ethanol recovery from aqueous solution.
Zeolite naa membranes were prepared reproducibly by a onetimeonly hydrothermal synthesis with a short reaction time of 3 h at 373 k using a gel with the composition. Using selectivity as the measure of the ability of the membrane to separate the species also allows comparison to gas permeation studies. In the years following kobers publication a number of papers were published describing membranes and processes for pervaporation. Pdf pebax membranes for water desalination by pervaporation. Enhanced pervaporation performance of multilayer pdms. Especially during the 1950s, the interest focused on pervaporation.
This process is used by a number of industries for several different processes, including purification and analysis, due to its simplicity and inline nature. In harsh environments, more robust membranes are required and feed can be liquid pervaporation or. In harsh environments, more robust membranes are required and feed can be liquid pervaporation or saturated vapor vapor permeation 0. The pervaporation experimental setup is shown in figure 3. The separation characteristics of binary alcoholwater. Introduction pervaporation and vapour permeation are similar membranebased separation processes whose basic difference lies in. Pervaporation of emulsion droplets for the templated. Membrane transport properties of pervaporation and vapor permeation in ethanolwater system using polyacrylonitrile and cellulose acetate membranes takehiko kataoka 1, toshinori tsuru 1, shinichi. Polyvinyl alcohol pva is one of the important membrane pervaporation materials for the dehydration of organic mixtures owing to its good chemical stability, filmforming ability and high hydrophilicity.
Pervaporationmt5009 analyzing hitech opportunities semester 2, 20112012 see siew hui a0077625x too kim hui a0077025j hubert giam. The mechanism of improvement on pervaporation properties was explained by reducing the free. Polyvinyl alcohol pva is one of the important membrane pervaporation materials for the dehydration of organic mixtures owing to its good chemical stability, filmforming ability and high hydrophilicity, especially high water permselectivity in pervaporation separation of aqueous ethanol solutions4. Gas permeation properties of 6fdabased copolyimide. Pervaporation free download as powerpoint presentation. The separation characteristics of binary alcoholwater mixtures were studied overa wide range of feed concentration and temperature using polymeric and zeoliticpervaporation membranes. Department of chemical and biological engineering, university of colorado, boulder, co 803090424, usa. Because distillations from aqueous solutions are energy intensive, pervaporation could be an energy savings separation alternative, as much less energy is potentially required compared to evaporation. The permselectivity of this material is related to the existence of free volume and to the hydrophobicity of the membrane surface.
Pervaporation of flavors with hydrophobic membrane. Membrane performance is represented in terms of flux, sorption coefficient, separation factor, and. Apr 15, 2010 the pervaporation experimental setup is shown in figure 3. Novel reactive distillation pervaporation coupled process. A novel bapdmbased aromatic polyamide membrane has been successfully prepared in this study. Membrane technology and applications, third edition. In recent years there has ken increased interest in the use of pervaporation membrane separation techniques for the selective separation of organic liquid mixtures, because of its high. Pervaporation of ethanolwater mixtures through poly1. The bapdm based aromatic polyamide membranes exhibited water selectivity during all process runs. Modeling and analysis on pervaporation separation of composite zeolite membranes by. Vtos crosslinked pdms membranes for recovery of ethanol.
Pervaporation performance in some previous studies and our study is listed in table 3. Pervaporation membranes have success in removal of components in dilute forms. Effect of coagulation medium on pvdf pervaporation membrane morphology for the separation of butanolwater mixture. Salt transport in polymeric pervaporation membrane pdf. Effect of coagulation medium on pvdf pervaporation membrane. Petro seps membrane distillation aqua sep systems can recover, purify, treat and clean hazardous water from mines, oil and gas fields, and industrial waste water. Pervaporation, in its simplest form, is a combination of membrane permeation and evaporation. For the hydrophilic pva membrane, the total flux at 55 0cfor the ethanolwater system decreased from 0. Synthesis and modification of polymer membranes for pervaporation and gas separation by shude xiao. Petro sep is a world leader in providing sophisticated and innovative membrane distillation and pervaporation membrane systems. Membrane 120 the separation of alcoholwater mixtures by pervaporation. In the past two decades, it has established itself as one of the most promising membrane technologies for. In addition the membrane is capable of dehydrating feed to ppm levels of.
Pervaporation of emulsion droplets for the templated assembly. Purchase pervaporation, vapour permeation and membrane distillation 1st edition. Dec 09, 2000 zeolite naa membranes were prepared reproducibly by a onetimeonly hydrothermal synthesis with a short reaction time of 3 h at 373 k using a gel with the composition al2o3. Pervaporation of ethanolwater mixtures using bacterial.
It is based on the use of fugacity gradients across the membrane, instead of concentration ones, as the driving force for mass transfer. Characterization of blended polymeric membranes for pervaporation of hydrazine hydrate. The principles of the pervaporation process are that the liquid mixture is in contact with the membrane. Pervaporation, vapour permeation and membrane distillation. Using pervaporation data in the calculation of vapour. The blend membrane exhibited a best performance, i. Separation of alcoholwater mixture by pervaporation. Trends in design and preparation of polymeric membranes for pervaporation. The separation characteristics of binary alcoholwater mixtures were studied over a wide range of feed concentration and temperature using polymeric and zeolitic pervaporation membranes. The pervaporation and vapor permeation performance of the above novel aromatic polyamide membranes for dehydrating an aqueous alcohol solution was investigated. Pervaporation is one of the most active areas in membrane research, and the pervaporation process has been shown to be an indispensable component for chemical separations.
Characterization of blended polymeric membranes for. Pervaporation is characterized by the imposition of a membrane layer between a liquid and a gaseous phase, with mass transfer to the gas side which occurs selectively across the membrane. Pdms membranes were prepared by crosslinking with vinyltriethoxysilane vtos on polyacrylonitrile pan substrate to increase hydrophobicity and improve pervaporation pv performance. Feb 22, 2011 the values of apparent activation energy for pervaporation transport are usually in the range of 5060 kj mol a1, depending on the nature of the membrane32,83,86,87. Recent membrane development for pervaporation processes. C for 6 and 4 hours respectively and they were kept in a desiccator at room temperature. The feed liquid is directly in contact with one side of the membrane, and the permeation of target compounds. Novel reactive distillation pervaporation coupled process for. Pervaporation pv has been considered as one of the most active and promising areas in membrane technologies in separating close boiling or azeotropic liquid mixtures, heat sensitive biomaterials, water or organics from its mixtures that are indispensable constituents for various important chemical and bioseparations. A detailed work on positron lifetime spectroscopic analysis was made for varieties of dense membranes in order to. For the hydrophilic pva membrane, the total flux at. Review fundamentals and applications of pervaporation through. A water bath was used to heat the feed solution to the desired temperature the heater had a thermostat and a thermometer immersed in the feed solution and a centrifugal pump ensured the recirculation of the feed solution about 5 cm 3 sec, laminar flow through the cross flow membrane cell, and back in the feed container. Journal preproof salt transport in polymeric pervaporation membrane dihua wu, aoran gao, xianshe feng pii.
Pervaporation was carried out for dehydration of isopropanol with the unconditioned and conditioned membranes, and the cstmc3 membrane showed the best pervaporation performance. At the permeate side, a partial pressure is generated by means of a vacuum pump. In the years following kobers publication a number of. Generally, one or more additional transition table 1 continued membrane feed solution temperaturec total fluxgm. Application of aromatic polyamide membranes for pervaporation. In recent years there has ken increased interest in the use of pervaporation membrane separation. Science and technology, general alcohol properties alcohol, denatured ethanol pervaporation methods polyvinylidene fluoride separation technology innovations. Effect of coagulation medium on pvdf pervaporation. In order to increase the yield of reaction, it is required to simultaneously remove the product of reaction. Using a pervaporation process, a surfacemodified hydrophobic membrane was used for recovery of esters which are volatile organic flavor compounds. Modeling and analysis on pervaporation separation of. Taking into account the close similarity between pervaporation and vapour permeation techniques, a method for employing pervaporation flux data in the modelling of vapour permeation modules is proposed.